SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	Acrylic acid 99%
Catalogue No. :	AL0110	Product form :	Substance
CAS Number :	79-10-7	EC Number :	201-177-9
Grade :		EC Index Number :	607-061-00-8
Chemical Formula :	C3H4O2 / CH2=CHCOOH	HSN Code :	29161100
Synonyms :	Propenoic Acid Ethylenecarboxylic Acid
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, Category 3 H226 Acute toxicity (oral), Category 4 H302 Acute toxicity (dermal), Category 4 H312 Acute toxicity (inhal.), Category 3 H331 Skin corrosion/irritation, Category 1A H314 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Hazardous to the aquatic environment Acute Hazard, Category 1 H400 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Xn; R20/21/22 C; R35 N; R50 R10 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS02 GHS05 GHS06 GHS09
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H226 - Flammable liquid and vapour. H302+H312 - Harmful if swallowed or in contact with skin H314 - Causes severe skin burns and eye damage. H331 - Toxic if inhaled. H335 - May cause respiratory irritation. H400 - Very toxic to aquatic life.
Precautionary statements (CLP) :	P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a doctor. P261 - Avoid breathing vapours, dust, fume, gas. EUH-statements : EUH071 - Corrosive to the respiratory tract.
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		ACRYLIC ACID (Stabilised) For Synthesis
CAS No. :		79-10-7
EC Index No. :		607-061-00-8
EC No. :		201-177-9
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
First-aid measures after skin contact :	Get medical advice/attention. Wash with plenty of water/…. Wash contaminated clothing before reuse.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion :	Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects : Causes severe skin burns and eye damage. Symptoms/effects after inhalation : May cause respiratory irritation. Toxic if inhaled. Symptoms/effects after skin contact : Harmful in contact with skin. Symptoms/effects after eye contact : Causes serious eye damage. Symptoms/effects after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media :	Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	Flammable liquid and vapour.
Explosion hazard :	May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting :	Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Very toxic to aquatic life.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	On land, sweep or shovel into suitable containers. Collect spillage.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling :	Do not breathe vapours. Take precautionary measures against static discharge. Use only non-sparking tools. Keep away from sources of ignition - No smoking. Avoid contact with skin and eyes.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment.
Storage conditions :	Keep container tightly closed. Store in a well-ventilated place.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or face shield
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	[In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid
Molecular mass :	72.06 g/mol
Colour :	Clear Colorless.
Odour :	acrid odor.
Odour threshold :	No data available
pH value :	1 - 2
Relative evaporation rate (butylacetate=1) :	1
Melting point :	13 °C
Freezing point :	No data available
Boiling point :	139 °C
Flash point :	46 °C
Auto-ignition temperature :	438 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	Flammable liquid and vapour.
Vapour pressure :	5 hPa at 20 °C
Relative vapour density at 20°C :	2.49
Density :	1.051 g/cm3
Solubility :	Water: Completely miscible
Log Pow :	0.46
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	0.02 - 0.137 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases. Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Harmful if swallowed. Dermal: Harmful in contact with skin. Inhalation: Toxic if inhaled.
Skin corrosion/irritation :	Causes severe skin burns and eye damage. pH: 1 - 2
Serious eye damage/irritation :	Serious eye damage, category 1, implicit pH: 1 - 2
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	May cause respiratory irritation. Additional information : Corrosive to the respiratory tract.
STOT-repeated exposure :	Not classified
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Harmful if swallowed. Harmful in contact with skin.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Very toxic to aquatic life.
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	Acrylic acid 99% (79-10-7) Log Pow 0.46
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Additional information :	Handle empty containers with care because residual vapours are flammable.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	2218
UN-No. (IMDG) :	2218
UN-No. (IATA) :	2218
UN-No. (ADN) :	2218
UN-No. (RID) :	2218
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	ACRYLIC ACID, STABILIZED
Proper Shipping Name (IMDG) :	ACRYLIC ACID, STABILIZED
Proper Shipping Name (IATA) :	ACRYLIC ACID, STABILIZED
Proper Shipping Name (ADN) :	ACRYLIC ACID, STABILIZED
Proper Shipping Name (RID) :	ACRYLIC ACID, STABILIZED
Transport document description (ADR) :	UN 2218, ACRYLIC ACID, STABILIZED, 8 (3), II ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 2218, ACRYLIC ACID, STABILIZED, 8 (3), II ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 2218, ACRYLIC ACID, STABILIZED, 8 (3), II ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 2218, ACRYLIC ACID, STABILIZED, 8 (3), II ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 2218, ACRYLIC ACID, STABILIZED, 8 (3), II ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	8 (3)
Danger labels :	8, 3
IMDG
Transport hazard class(es) :	8 (3)
Danger labels :	8, 3
IATA
Transport hazard class(es) :	8 (3)
Danger labels :	8, 3
ADN
Transport hazard class(es) :	8 (3)
Danger labels :	8, 3
RID
Transport hazard class(es) :	8 (3)
Danger labels :	8, 3
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : CF1 Limited quantities (ADR) : 1l Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR): T7 Portable tank and bulk container special provisions (ADR): TP2 Tank code (ADR): L4BN Vehicle for tank carriage: FL Transport category (ADR):2 Special provisions for carriage - Operation (ADR): S2 Hazard identification number (Kemler No.): 839 Orange plates: Tunnel restriction code (ADR): D/E EAC code: -2W APP code: A(fl)
- Transport by sea
Limited quantities (IMDG):1L Excepted quantities (IMDG): E2 Packing instructions (IMDG): P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG): T7 Tank special provisions (IMDG): TP2 EmS-No. (Fire): F-E EmS-No. (Spillage): S-C Stowage category (IMDG):C Stowage and handling (IMDG): SW1, SW2 Flash point (IMDG): 54°C o.c. MFAG-No: 132P
- Air transport
PCA Excepted quantities (IATA): E2 PCA Limited quantities (IATA): Y840 PCA limited quantity max net quantity (IATA): 0.5L PCA packing instructions (IATA): 851 PCA max net quantity (IATA): 1L CAO packing instructions (IATA): 855 CAO max net quantity (IATA): 30L ERG code (IATA): 8F
- Inland waterway transport
Classification code (ADN): CF1 Limited quantities (ADN): 1L Excepted quantities (ADN): E2 Carriage permitted (ADN):T Equipment required (ADN): PP, EP, EX, A Ventilation (ADN): VE01 Number of blue cones/lights (ADN):1
- Rail transport
Classification code (RID): CF1 Limited quantities (RID): 1L Excepted quantities (RID): E2 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : P15 Portable tank and bulk container instructions (RID): T7 Portable tank and bulk container special provisions (RID): TP2 Tank codes for RID tanks (RID) : L4BN Transport category (RID) : 2 Colis express (express parcels) (RID) : CE6 Hazard identification number (RID) : 839
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions Acrylic acid 99% is not on the REACH Candidate List Acrylic acid 99% is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 2, significant hazard to water (Classification according to AwSV; ID No. 11) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed
Denmark
Class for fire hazard : Class II-1 Store unit : 5 liter Classification remarks : R10 ; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3 Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1 Flam. Liq. 3 Flammable liquids, Category 3 Skin Corr. 1A Skin corrosion/irritation, Category 1A STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H226 Flammable liquid and vapour. H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H331 Toxic if inhaled. H335 May cause respiratory irritation. H400 Very toxic to aquatic life. EUH071 Corrosive to the respiratory tract. R10 Flammable R20/21/22 Harmful by inhalation, in contact with skin and if swallowed R35 Causes severe burns R50 Very toxic to aquatic organisms C Corrosive N Dangerous for the environment Xn Harmful