4-CHLOROANILINE For Synthesis |
| Synonyms : 4-Chlorobenzenamine; p-Chloroaniline |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
|||
|---|---|---|---|
1.1 Product identifier |
|||
| Chemical Name : | p-CHLORO ANILINE (for synthesis) (4-chloro aniline) | ||
| Catalogue No. : | AL1262 | Product form : | Substance |
| CAS Number : | 106-47-8 | EC Number : | 203-401-0 |
| Grade : | EC Index Number : | 612-137-00-9 | |
| Chemical Formula : | HSN Code : | 29214211 | |
| Synonyms : | 4-Chlorobenzenamine; p-Chloroaniline | ||
| Chemical Structure : |
|
||
1.2 Relevant identified uses of the substance or mixture and uses advised against |
|||
| Use of the substance/mixture : | Industrial For professional use only | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
|||
| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
||
1.4 Emergency Contact Details |
|||
| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
||
SECTION 2: Hazards identification |
|
|---|---|
2.1 Classification of the substance or mixture |
|
| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
|
Acute toxicity (oral), Category 3 H301 Acute toxicity (dermal), Category 3 H311 Acute toxicity (inhal.), Category 3 H331 Skin sensitisation, Category 1 H317 Carcinogenicity, Category 1B H350 Hazardous to the aquatic environment Chronic Hazard, Category 1 H410 Full text of H statements : see section 16 |
|
| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Carc.Cat.2; R45 T; R23/24/25 R43 N; R50/53 Full text of R-phrases: see section 16 |
|
| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
|
| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS06
 GHS08
 GHS09
|
| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H317 - May cause an allergic skin reaction. H350 - May cause cancer. H410 - Very toxic to aquatic life with long lasting effects. |
| Precautionary statements (CLP) : | P201 - Obtain special instructions before use. P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P301+P310 - IF SWALLOWED: Immediately call a doctor. P311 - Call a doctor. P261 - Avoid breathing vapours, spray, dust, fume, gas. |
2.3 Other hazards |
|
| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
|||
|---|---|---|---|
3.1. Substance |
|||
| Name : | 4-CHLOROANILINE FOR SYNTHESIS | ||
| CAS No. : | 106-47-8 | ||
| EC Index No. : | 612-137-00-9 | ||
| EC No. : | 203-401-0 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
|||
| Not applicable | |||
SECTION 4: First aid measures |
|
|---|---|
4.1 Description of first aid measures |
|
| First-aid measures after inhalation : | Assure fresh air breathing. If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
| First-aid measures after skin contact : | Wash with plenty of water/…. Wash contaminated clothing before reuse. Get medical advice/attention. |
| First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth. Obtain emergency medical attention. |
4.2 Most important symptoms and effects, both acute and delayed |
|
| Symptoms relating to use : | Symptoms/effects : May cause cancer. Symptoms/effects after inhalation : Toxic if inhaled. Symptoms/effects after skin contact : Toxic in contact with skin. May cause an allergic skin reaction. Symptoms/effects after ingestion : Toxic if swallowed. |
4.3 Indication of any immediate medical attention and special treatment needed |
|
| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
|
|---|---|
5.1 Extinguishing media |
|
| Suitable extinguishing media : | Carbon dioxide. Dry powder. Foam. Water spray. |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
|
| Special procedures : | No additional information available |
5.3 Advice for firefighters |
|
| Protection during firefighting : | Do not enter fire area without proper protective equipment, including respiratory protection. |
SECTION 6: Accidental release measures |
|
|---|---|
6.1 Personal precautions, protective equipment and emergency procedures |
|
6.1.1. For non-emergency personnel |
|
| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
|
| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Ventilate area. |
6.2 Environmental precautions |
|
| Very toxic to aquatic life with long lasting effects. | |
6.3 Methods and material for containment and cleaning up |
|
| Methods for cleaning up : | On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. |
6.4 Reference to other sections |
|
| Reference : | No additional information available |
SECTION 7: Handling and storage |
|
|---|---|
7.1 Precautions for safe handling |
|
| Precautions for safe handling : | Do not breathe vapours. Obtain special instructions before use. Avoid contact with skin and eyes. |
| Hygiene measures : | Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. |
7.2 Conditions for safe storage, including any incompatibilities |
|
| Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
|
| No additional information available | |
SECTION 8: Exposure controls/personal protection |
|
|---|---|
8.1 Control parameters |
|
| No additional information available | |
8.2 Exposure controls |
|
| Hand protection : | Protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | [In case of inadequate ventilation] wear respiratory protection. |
SECTION 9: Physical and chemical properties |
|
|---|---|
9.1 Information on basic physical and chemical properties |
|
| Physical state : | Solid |
| Molecular mass : | 127.57 g/mol |
| Colour : | Colorless crystals. |
| Odour : | sweetish. |
| Odour threshold : | No data available |
| pH value : | 6.9 at 1.00000 g/l at 20 °C |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | 72.5 °C |
| Freezing point : | No data available |
| Boiling point : | 232 °C |
| Flash point : | > 104.44 °C |
| Auto-ignition temperature : | No data available |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | No data available |
| Relative vapour density at 20°C : | No data available |
| Density : | 1.14 g/cm3 |
| Solubility : | Water: Partially soluble in cold water |
| Log Pow : | 2.12 |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | No data available |
9.2 Other information |
|
| No additional information available | |
SECTION 10: Stability and reactivity |
|
|---|---|
10.1 Reactivity |
|
| No additional information available | |
10.2 Chemical stability |
|
| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
|
| No additional information available | |
10.4 Conditions to avoid |
|
| Air contact. Direct sunlight. Moisture. Overheating. | |
10.5 Incompatible materials |
|
| No additional information available | |
10.6 Hazardous decomposition products |
|
| No additional information available |
SECTION 11: Toxicological information |
|
|---|---|
11.1 Information on toxicological effects |
|
| Acute toxicity : | Oral: Toxic if swallowed. Dermal: Toxic in contact with skin. Inhalation: Toxic if inhaled. |
| Skin corrosion/irritation : | Not classified pH: 6.9 at 1.00000 g/l at 20 °C |
| Serious eye damage/irritation : | Not classified pH: 6.9 at 1.00000 g/l at 20 °C |
| Respiratory or skin sensitisation : | May cause an allergic skin reaction. |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | May cause cancer. |
| STOT-single exposure : | Not classified |
| STOT-repeated exposure : | Not classified |
| Aspiration hazard : | Not classified |
| Potential adverse human health effects and symptoms : | Toxic if swallowed. Toxic in contact with skin. |
SECTION 12: Ecological information |
|
|---|---|
12.1 Toxicity |
|
| Toxicity information : | Ecology - water : Very toxic to aquatic life with long lasting effects. |
12.2 Persistence - degradability |
|
| Persistence - degradability : | 4-CHLOROANILINE FOR SYNTHESIS (106-47-8) Persistence and degradability May cause long-term adverse effects in the environment. |
12.3 Bioaccumulative potential |
|
| Bioaccumulative potential : | 4-CHLOROANILINE FOR SYNTHESIS (106-47-8) Log Pow 2.12 |
12.4 Mobility in soil |
|
| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
|
| No additional information available | |
12.6 Other adverse effects |
|
| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
|
|---|---|
13.1 Waste treatment methods |
|
| Product/Packaging disposal recommendations : | Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. |
| Ecology - waste materials : | Hazardous waste due to toxicity. |
SECTION 14: Transport information |
|
|---|---|
| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
|
| UN-No. (ADR) : | 2018 |
| UN-No. (IMDG) : | 2018 |
| UN-No. (IATA) : | 2018 |
| UN-No. (ADN) : | 2018 |
| UN-No. (RID) : | 2018 |
14.2. UN proper shipping name |
|
| Proper Shipping Name (ADR) : | CHLOROANILINES, SOLID |
| Proper Shipping Name (IMDG) : | CHLOROANILINES, SOLID |
| Proper Shipping Name (IATA) : | CHLOROANILINES, SOLID |
| Proper Shipping Name (ADN) : | CHLOROANILINES, SOLID |
| Proper Shipping Name (RID) : | CHLOROANILINES, SOLID |
| Transport document description (ADR) : | UN 2018, CHLOROANILINES, SOLID, 6.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IMDG) : | UN 2018, CHLOROANILINES, SOLID, 6.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IATA) : | UN 2018, CHLOROANILINES, SOLID, 6.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (ADN) : | UN 2018, CHLOROANILINES, SOLID, 6.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (RID) : | UN 2018, CHLOROANILINES, SOLID, 6.1, II ENVIRONMENTALLY HAZARDOUS |
14.3. Transport hazard class(es) |
|
| ADR | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1 
|
| IMDG | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
|
| IATA | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
|
| ADN | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
|
| RID | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
|
14.4. Packing group |
|
| Packing group (ADR) : | II |
| Packing group (IMDG) : | II |
| Packing group (IATA) : | II |
| Packing group (ADN) : | II |
| Packing group (RID) : | II |
14.5. Environmental hazards |
|
| Dangerous for the environment : | Yes |
| Marine pollutant : | Yes |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
|
| - Overland transport | |
|
Classification code (ADR) : T2 Limited quantities (ADR) : 500g Excepted quantities (ADR) : E4 Packing instructions (ADR) : P002, IBC08 Special packing provisions (ADR) : B4 Mixed packing provisions (ADR) : MP10 Portable tank and bulk container instructions (ADR) : T3 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAH, L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Packages (ADR) : V11 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S9, S19 Hazard identification number (Kemler No.) : 60 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : 2X |
|
| - Transport by sea | |
|
Packing instructions (IMDG) : P002 IBC packing instructions (IMDG) : IBC08 IBC special provisions (IMDG) : B21, B4 Tank instructions (IMDG) : T3 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-A Stowage category (IMDG) : A Properties and observations (IMDG) : Crystalline solid. Melting point of pure para-chloroaniline: 70°C approximately. Toxic if swallowed, by skin contact or by dust inhalation. MFAG-No : 152 |
|
| - Air transport | |
|
PCA Excepted quantities (IATA) : E4 PCA Limited quantities (IATA) : Y644 PCA limited quantity max net quantity (IATA) : 1kg PCA packing instructions (IATA) : 669 PCA max net quantity (IATA) : 25kg CAO packing instructions (IATA) : 676 CAO max net quantity (IATA) : 100kg ERG code (IATA) : 6L |
|
| - Inland waterway transport | |
|
Classification code (ADN) : T2 Special provisions (ADN) : 802 Limited quantities (ADN) : 500 g Excepted quantities (ADN) : E4 Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 2 |
|
| - Rail transport | |
|
Classification code (RID) : T2 Excepted quantities (RID) : E4 Packing instructions (RID) : P002, IBC08 Special packing provisions (RID) : B4 Mixed packing provisions (RID) : MP10 Portable tank and bulk container instructions (RID) : T3 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAH, L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage – Packages (RID) : W11 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE9 Hazard identification number (RID) : 60 |
|
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
|
| Not applicable | |
SECTION 15: Regulatory information |
|---|
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions 4-CHLOROANILINE FOR SYNTHESIS is not on the REACH Candidate List 4-CHLOROANILINE FOR SYNTHESIS is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| Reference to AwSV : Water hazard class (WGK) 3, severe hazard to water (Classification according to AwSV; ID No. 224) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Netherlands |
| SZW-lijst van kankerverwekkende stoffen : 4-CHLOROANILINE FOR SYNTHESIS is listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed |
| Denmark |
| Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
|||||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
|
|||||||||||||||||||||