BENZYLAMINE For Synthesis |
| Synonyms : a-Aminotoluene |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | BENZYLAMINE (for synthesis) | ||
| Catalogue No. : | AL0650 | Product form : | Substance |
| CAS Number : | 100-46-9 | EC Number : | 202-854-1 |
| Grade : | EC Index Number : | 612-047-00-X | |
| Chemical Formula : | HSN Code : | 29214990 | |
| Synonyms : | a-Aminotoluene | ||
| Chemical Structure : |
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1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Acute toxicity (oral), Category 4 H302 Acute toxicity (dermal), Category 4 H312 Skin corrosion/irritation, Category 1B H314 Full text of classification categories and H statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Xn; R21/22 C; R34 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS05
 GHS07
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| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H302+H312 - Harmful if swallowed or in contact with skin H314 - Causes severe skin burns and eye damage |
| Precautionary statements (CLP) : | P280 - Wear protective gloves, protective clothing, eye protection, face protection P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a doctor |
2.3 Other hazards |
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| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Name : | BENZYLAMINE FOR SYNTHESIS | ||
| CAS No. : | 100-46-9 | ||
| EC Index No. : | 612-047-00-X | ||
| EC No. : | 202-854-1 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. |
| First-aid measures after skin contact : | Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see ... on this label). |
| First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth out with water. If you feel unwell, seek medical advice. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/injuries after inhalation : May cause respiratory irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye irritation. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | Carbon dioxide. Dry powder. Foam. Water spray. |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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| Special procedures : | No additional information available |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not enter fire area without proper protective equipment, including respiratory protection. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Ventilate area. |
6.2 Environmental precautions |
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| Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | Collect spillage. On land, sweep or shovel into suitable containers. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Precautions for safe handling : | Avoid contact with skin and eyes. Do not breathe vapours. Provide good ventilation in process area to prevent formation of vapour. |
| Hygiene measures : | Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | Protective gloves |
| Eye protection : | Chemical goggles or face shield |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | Wear respiratory protection |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Liquid Colour |
| Colour : | Colorless to pale yellow. |
| Odour : | amine like. |
| Odour threshold : | No data available |
| pH value : | 11.4 at 100 g/l at 20 °C |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | 10 °C |
| Freezing point : | No data available |
| Boiling point : | 184 - 185 °C |
| Flash point : | 65 °C |
| Auto-ignition temperature : | 405 °C |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | 0.1 kPa (at 20°C) |
| Relative vapour density at 20°C : | 3.7 |
| Density : | 0.981 g/cm3 |
| Solubility : | Water: Soluble in water |
| Log Pow : | 1.09 |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | 0.007 - 0.082 vol % |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| Thermal decomposition generates : Corrosive vapours. | |
10.2 Chemical stability |
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| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
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| No additional information available | |
10.4 Conditions to avoid |
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| No additional information available | |
10.5 Incompatible materials |
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| No additional information available | |
10.6 Hazardous decomposition products |
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| Thermal decomposition generates : Corrosive vapours. |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Oral: Harmful if swallowed. Dermal: Harmful in contact with skin. |
| Skin corrosion/irritation : | Causes severe skin burns and eye damage. pH: 11.4 at 100 g/l at 20 °C |
| Serious eye damage/irritation : | Serious eye damage, category 1, implicit pH: 11.4 at 100 g/l at 20 °C |
| Respiratory or skin sensitisation : | Not classified |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Not classified |
| Reproductive toxicity : | Not classified |
| Specific target organ toxicity (single exposure) : | Not classified |
| Specific target organ toxicity (repeated exposure) : | Not classified |
| Aspiration hazard : | Not classified |
| Potential adverse human health effects and symptoms : | Harmful if swallowed. Harmful in contact with skin. |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | No additional information available |
12.2 Persistence - degradability |
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| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | BENZYLAMINE FOR SYNTHESIS (100-46-9) Log Pow 1.09 |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| No additional information available | |
12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to ... |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 2735 |
| UN-No. (IMDG) : | 2735 |
| UN-No. (IATA) : | 2735 |
| UN-No. (ADN) : | 2735 |
| UN-No. (RID) : | 2735 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S. |
| Proper Shipping Name (IMDG) : | AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S. |
| Proper Shipping Name (IATA) : | AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S. |
| Proper Shipping Name (ADN) : | AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S. |
| Proper Shipping Name (RID) : | AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S. |
| Transport document description (ADR) : | UN 2735, AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S., 8, II |
| Transport document description (IMDG) : | UN 2735, AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S., 8, II |
| Transport document description (IATA) : | UN 2735, AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S., 8, II |
| Transport document description (ADN) : | UN 2735, AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S., 8, II |
| Transport document description (RID) : | UN 2735, AMINES, LIQUID, CORROSIVE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, N.O.S., 8, II |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8 
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| IMDG | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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| IATA | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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| ADN | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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| RID | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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14.4. Packing group |
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| Packing group (ADR) : | II |
| Packing group (IMDG) : | II |
| Packing group (IATA) : | II |
| Packing group (ADN) : | II |
| Packing group (RID) : | II |
14.5. Environmental hazards |
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| Dangerous for the environment : | No |
| Marine pollutant : | No |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : C7 Special provision (ADR) : 274 Limited quantities (ADR) : 1L Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T11 Portable tank and bulk container special provisions (ADR) : TP1, TP27 Tank code (ADR) : L4BN Vehicle for tank carriage : AT Transport category (ADR) : 2 Hazard identification number (Kemler No.) : 80 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2X APP code : B |
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| - Transport by sea | |
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Special provision (IMDG) : 274 Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T11 Tank special provisions (IMDG) : TP1, TP27 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : A Segregation (IMDG) : SG35 MFAG-No : 153 |
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| - Air transport | |
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PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y840 PCA limited quantity max net quantity (IATA) : 0.5L PCA packing instructions (IATA) : 851 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 855 CAO max net quantity (IATA) : 30L Special provision (IATA) : A3 ERG code (IATA) : 8L |
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| - Inland waterway transport | |
| Not regulated | |
| - Rail transport | |
| Not regulated | |
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions BENZYLAMINE FOR SYNTHESIS is not on the REACH Candidate List BENZYLAMINE FOR SYNTHESIS is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| AwSV/VwVwS Annex reference : Water hazard class (WGK) 1, slightly hazardous to water (Classification according to VwVwS, Annex 3; WGK No 2324) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Denmark |
| Class for fire hazard : Class III-1 Store unit : 50 liter Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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