p-CHLORO-o-NITROANILINE For Synthesis

p-CHLORO-o-NITROANILINE For Synthesis

Synonyms : 4-Chloro-2-nitroaniline

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : p-CHLORO-o-NITROANILINE (for synthesis)(4-chloro-2-nitroaniline)
Catalogue No. : AL1311 Product form : Substance
CAS Number : 89-63-4 EC Number :
Grade : EC Index Number :
Chemical Formula : HSN Code : 29214226
Synonyms : 4-Chloro-2-nitroaniline
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial For professional use only
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (oral),
Category 1
H300
Acute toxicity (dermal),
Category 1
H310
Acute toxicity (inhal.),
Category 2
H330
Specific target organ
toxicity Repeated
exposure, Category 2
H373
Hazardous to the aquatic
environment Chronic
Hazard, Category 2
H411
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Muta.Cat.3; R68
T+; R26/27/28
N; R51/53
R33
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS06GHS06 GHS08GHS08 GHS09GHS09
Signal word (CLP) : Danger
Hazard statements (CLP) : H300+H310+H330 - Fatal if swallowed, in contact with skin or if inhaled
H373 - May cause damage to organs through prolonged or repeated exposure.
H411 - Toxic to aquatic life with long lasting effects.
Precautionary statements (CLP) : P260 - Do not breathe vapours, spray, dust, fume, gas.
P264 - Wash hands, forearms and face thoroughly after handling.
P273 - Avoid release to the environment.
P280 - Wear protective gloves, protective clothing, eye protection, face protection.
P284 - Wear respiratory protection.
P301+P310 - IF SWALLOWED: Immediately call a doctor.
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : p-CHLORO-o-NITROANILINE FOR SYNTHESIS
CAS No. : 89-63-4
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing.
First-aid measures after skin contact : Immediately call a POISON CENTER/doctor. Gently wash with plenty of soap and
water. Take off immediately all contaminated clothing. Wash contaminated clothing
before reuse.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously
with water for several minutes.
First-aid measures after ingestion : Rinse mouth. Immediately call a POISON CENTER/doctor.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/effects : May cause damage to organs.
Symptoms/effects after skin contact : Fatal in contact with skin.
Symptoms/effects after ingestion : Fatal if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as
possible. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Do not get in eyes, on skin, or on clothing. Avoid contact with skin and eyes. Do not breathe vapours.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid
Molecular mass : 172.57 g/mol
Colour : Orange powder.
Odour : No data available
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 115 °C
Freezing point : No data available
Boiling point : No data available
Flash point : 191 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20°C : No data available
Solubility : Water: Insoluble
Log Pow : 2.64
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Air contact. Direct sunlight. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Oral: Fatal if swallowed. Dermal: Fatal in contact with skin. Inhalation: Fatal if
inhaled.
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not
STOT-single exposure : Not classified
STOT-repeated exposure : May cause damage to organs through prolonged or repeated exposure.
Additional information : There are potential chronic health effects to consider
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Fatal if swallowed. Fatal in contact with skin.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : Ecology - water : Toxic to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability : p-CHLORO-o-NITROANILINE FOR SYNTHESIS (89-63-4) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential : p-CHLORO-o-NITROANILINE FOR SYNTHESIS (89-63-4) Log Pow 2.64
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Ecology - waste materials : Hazardous waste due to toxicity.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2237
UN-No. (IMDG) : 2237
UN-No. (IATA) : 2237
UN-No. (ADN) : 2237
UN-No. (RID) : 2237
14.2. UN proper shipping name
Proper Shipping Name (ADR) : CHLORONITROANILINES
Proper Shipping Name (IMDG) : CHLORONITROANILINES
Proper Shipping Name (IATA) : CHLORONITROANILINES
Proper Shipping Name (ADN) : CHLORONITROANILINES
Proper Shipping Name (RID) : CHLORONITROANILINES
Transport document description (ADR) : UN 2237, CHLORONITROANILINES, 6.1, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) : UN 2237, CHLORONITROANILINES, 6.1, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) : UN 2237, CHLORONITROANILINES, 6.1, III ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) : UN 2237, CHLORONITROANILINES, 6.1, III ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) : UN 2237, CHLORONITROANILINES, 6.1, III ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 6.1
Danger labels : 6.1
IMDG
Transport hazard class(es) : 6.1
Danger labels : 6.1
IATA
Transport hazard class(es) : 6.1
Danger labels : 6.1
ADN
Transport hazard class(es) : 6.1
Danger labels : 6.1
RID
Transport hazard class(es) : 6.1
Danger labels : 6.1
14.4. Packing group
Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : T2
Limited quantities (ADR) : 5kg
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P002, IBC08, LP02, R001
Special packing provisions (ADR) : B3
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container
instructions (ADR)
: T1
Portable tank and bulk container special
provisions (ADR)
: TP33
Tank code (ADR) : SGAH, L4BH
Tank special provisions (ADR) : TU15, TE19
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage - Bulk
(ADR)
: VC1, VC2, AP7
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV13, CV28
Special provisions for carriage - Operation
(ADR)
: S9
Hazard identification number (Kemler No.) : 60
Orange plates :
Tunnel restriction code (ADR) : E
EAC code : 2X
- Transport by sea
Packing instructions (IMDG) : P002, LP02
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B3
Tank instructions (IMDG) : T1
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-A
Stowage category (IMDG) : A
Properties and observations (IMDG) : Yellow or orange crystalline powders or needles. Insoluble in water. Toxic if
swallowed, by skin contact or by dust inhalation.
MFAG-No : 153
- Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y645
PCA limited quantity max net quantity
(IATA)
: 10kg
PCA packing instructions (IATA) : 670
PCA max net quantity (IATA) : 100kg
CAO packing instructions (IATA) : 677
CAO max net quantity (IATA) : 200kg
ERG code (IATA) : 6L
- Inland waterway transport
Classification code (ADN) : T2
Special provisions (ADN) : 802
Limited quantities (ADN) : 5 kg
Excepted quantities (ADN) : E1
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : T2
Excepted quantities (RID) : E1
Packing instructions (RID) : P002, IBC08, LP02, R001
Special packing provisions (RID) : B3
Mixed packing provisions (RID) : MP10
Portable tank and bulk container
instructions (RID)
: T1
Portable tank and bulk container special
provisions (RID)
: TP33
Tank codes for RID tanks (RID) : SGAH, L4BH
Special provisions for RID tanks (RID) : TU15
Transport category (RID) : 2
Special provisions for carriage – Bulk
(RID)
: VC1, VC2, AP7
Special provisions for carriage - Loading,
unloading and handling (RID)
: CW13, CW28, CW31
Colis express (express parcels) (RID) : CE11
Hazard identification number (RID) : 60
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
p-CHLORO-o-NITROANILINE FOR SYNTHESIS is not on the REACH Candidate List
p-CHLORO-o-NITROANILINE FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 2, significant hazard to water (Classification according to
AwSV; ID No. 706)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Borstvoeding
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen-
Vruchtbaarheid
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Ontwikkeling
: The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements:
Acute Tox. 1 (Dermal) Acute toxicity (dermal), Category 1
Acute Tox. 1 (Oral) Acute toxicity (oral), Category 1
Acute Tox. 2 (Inhalation) Acute toxicity (inhal.), Category 2
Aquatic Chronic 2 Hazardous to the aquatic environment — Chronic Hazard, Category 2
STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2
H300 Fatal if swallowed.
H310 Fatal in contact with skin.
H330 Fatal if inhaled.
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.
R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed
R33 Danger of cumulative effects
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R68 Possible risk of irreversible effects
N Dangerous for the environment
T+ Very toxic