tert-BUTYLAMINE For Synthesis

tert-BUTYLAMINE For Synthesis

Synonyms : 2-Amine-2-methylpropane

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : tert-BUTYLAMINE
Catalogue No. : AL0962 Product form : Substance
CAS Number : 75-64-9 EC Number :
Grade : EC Index Number :
Chemical Formula : HSN Code : 29211190
Synonyms : 2-Amino-2-methylpropane
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial For professional use only
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids,
Category 2
H225
Skin corrosion/irritation,
Category 1A
H314
Acute toxicity (inhal.),
Category 4
H332
Acute toxicity (oral),
Category 4
H302
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
F; C; T; R11-20/22-35
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS02GHS02 GHS05GHS05 GHS07GHS07
Signal word (CLP) : Danger
Hazard statements (CLP) : H225 - Highly flammable liquid and vapour.
H302+H332 - Harmful if swallowed or if inhaled
H314 - Causes severe skin burns and eye damage.
Precautionary statements (CLP) : P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P260 - Do not breathe dust/fume/gas/mist/vapours/spray.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P310 - Immediately call a POISON CENTER/doctor
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : tert-BUTYLAMINE FOR SYNTHESIS
CAS No. : 75-64-9
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Immediately call a
POISON CENTER/doctor.
First-aid measures after skin contact : Rinse skin with water/shower. Take off immediately all contaminated clothing.
Immediately call a POISON CENTER/doctor.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion : Rinse mouth. Call a POISON CENTER/doctor if you feel unwell. Do NOT induce
vomiting. Immediately call a POISON CENTER/doctor.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/effects : Causes severe skin burns and eye damage.
Symptoms/effects after inhalation : Harmful if inhaled.
Symptoms/effects after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media : Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Fire hazard : Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open
flames. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures : Avoid contact with skin, eyes and clothing.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Stop release.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Clean up immediately by sweeping or vacuum.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling : No open flames. No smoking. Use only non-sparking tools. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact during pregnancy/while nursing.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands, forearms and face thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed.
Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Comply with applicable regulations.
Storage conditions : Keep in fireproof place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or face shield
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid
Molecular mass : 73.14 g/mol
Colour : Clear Colorless.
Odour : ammonia odor.
Odour threshold : No data available
pH value : 12.1 at 100 g/l at 25 °C
Relative evaporation rate (butylacetate=1) : No data available
Melting point : -67 °C
Freezing point : No data available
Boiling point : 46 °C
Flash point : -38 °C
Auto-ignition temperature : 380 °C
Decomposition temperature : No data available
Flammability (solid, gas) : Extremely Flammable Highly flammable liquid and v
Vapour pressure : 392.9 hPa at 20 °C
Relative vapour density at 20°C : 2.53
Density : 0.696 g/cm3
Solubility : Water: Completely soluble
Log Pow : 0.4
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : 0.017 - 0.098 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2 Chemical stability
Highly flammable liquid and vapour. May form flammable/explosive vapour-air mixture.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Direct sunlight.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases. Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Inhalation: Harmful if inhaled. Oral: Harmful if swallowed.
Skin corrosion/irritation : Causes severe skin burns and eye damage.
pH: 12.1 at 100 g/l at 25 °C
Serious eye damage/irritation : Serious eye damage, category 1, implicit
pH: 12.1 at 100 g/l at 25 °C
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful if swallowed.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : tert-BUTYLAMINE FOR SYNTHESIS (75-64-9) Log Pow 0.4
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Additional information : Handle empty containers with care because residual vapours are flammable.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2734
UN-No. (IMDG) : 2734
UN-No. (IATA) : 2734
UN-No. (ADN) : 2734
UN-No. (RID) : 2734
14.2. UN proper shipping name
Proper Shipping Name (ADR) : AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. / POLYAMINES, LIQUID,
CORROSIVE, FLAMMABLE, N.O.S.
Proper Shipping Name (IMDG) : AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. / POLYAMINES, LIQUID,
CORROSIVE, FLAMMABLE, N.O.S.
Proper Shipping Name (IATA) : AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. / POLYAMINES, LIQUID,
CORROSIVE, FLAMMABLE, N.O.S.
Proper Shipping Name (ADN) : AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. / POLYAMINES, LIQUID,
CORROSIVE, FLAMMABLE, N.O.S.
Proper Shipping Name (RID) : AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. / POLYAMINES, LIQUID,
CORROSIVE, FLAMMABLE, N.O.S.
Transport document description (ADR) : UN 2734, AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S., 8 (3), I
Transport document description (IMDG) : UN 2734, AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S., 8 (3), I
Transport document description (IATA) : UN 2734, AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S., 8 (3), I
Transport document description (ADN) : UN 2734, AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S., 8 (3), I
Transport document description (RID) : UN 2734, AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. / POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S., 8 (3), I
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 8 (3)
Danger labels : 8, 3
IMDG
Transport hazard class(es) : 8 (3)
Danger labels : 8, 3
IATA
Transport hazard class(es) : 8 (3)
Danger labels : 8, 3
ADN
Transport hazard class(es) : 8 (3)
Danger labels : 8, 3
RID
Transport hazard class(es) : 8 (3)
Danger labels : 8, 3
14.4. Packing group
Packing group (ADR) : I
Packing group (IMDG) : I
Packing group (IATA) : I
Packing group (ADN) : I
Packing group (RID) : I
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : CF1
Special provisions (ADR) : 274
Limited quantities (ADR) : 0
Excepted quantities (ADR) : E0
Packing instructions (ADR) : P001
Mixed packing provisions (ADR) : MP8, MP17
Portable tank and bulk container
instructions (ADR)
: T14
Portable tank and bulk container special
provisions (ADR)
: TP2, TP27
Tank code (ADR) : L10BH
Vehicle for tank carriage : FL
Transport category (ADR) : 1
Special provisions for carriage - Operation
(ADR)
: S2, S14
Hazard identification number (Kemler No.) : 883
Orange plates :
Tunnel restriction code (ADR) : D/E
EAC code : •2W
APP code : A(fl)
- Transport by sea
Special provisions (IMDG) : 274
Packing instructions (IMDG) : P001
Tank instructions (IMDG) : T14
Tank special provisions (IMDG) : TP2, TP27
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-C
Stowage category (IMDG) : A
Segregation (IMDG) : SG35
Properties and observations (IMDG) : Colourless to yellowish flammable liquids or solutions with a pungent odour. Miscible
with water. When involved in a fire, evolve toxic gases. Corrosive to most metals,
especially to copper and its alloys. Reacts violently with acids. Cause burns to skin,
eyes and mucous membranes.
MFAG-No : 132
- Air transport
PCA Excepted quantities (IATA) : E0
PCA Limited quantities (IATA) : Forbidden
PCA limited quantity max net quantity
(IATA)
: Forbidden
PCA packing instructions (IATA) : 850
PCA max net quantity (IATA) : 0.5L
CAO packing instructions (IATA) : 854
CAO max net quantity (IATA) : 2.5L
ERG code (IATA) : 8F
- Inland waterway transport
Classification code (ADN) : CF1
Special provisions (ADN) : 274
Limited quantities (ADN) : 0
Excepted quantities (ADN) : E0
Equipment required (ADN) : PP, EP, EX, A
Ventilation (ADN) : VE01
Number of blue cones/lights (ADN) : 1
- Rail transport
Classification code (RID) : CF1
Special provisions (RID) : 274
Limited quantities (RID) : 0
Excepted quantities (RID) : E0
Packing instructions (RID) : P001
Mixed packing provisions (RID) : MP8, MP17
Portable tank and bulk container
instructions (RID)
: T14
Portable tank and bulk container special
provisions (RID)
: TP2, TP27
Tank codes for RID tanks (RID) : L10BH
Special provisions for RID tanks (RID) : TU38, TE22
Transport category (RID) : 1
Hazard identification number (RID) : 883
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
tert-BUTYLAMINE FOR SYNTHESIS is not on the REACH Candidate List
tert-BUTYLAMINE FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 2, significant hazard to water (Classification according to
AwSV; ID No. 1510)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Borstvoeding
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen-
Vruchtbaarheid
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Ontwikkeling
: The substance is not listed
Denmark
Classification remarks : Emergency management guidelines for the storage of flammable liquids must be
followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements:
Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Flam. Liq. 2 Flammable liquids, Category 2
Skin Corr. 1A Skin corrosion/irritation, Category 1A
H225 Highly flammable liquid and vapour.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H332 Harmful if inhaled.
F Highly flammable