SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	3-CHLOROTOLUENE (for synthesis)
Catalogue No. :	AL1345	Product form :	Substance
CAS Number :	108-41-8	EC Number :
Grade :		EC Index Number :
Chemical Formula :		HSN Code :	29039990
Synonyms :	1-Chloro-3-methylbenzene; 3-methylchlorobenzene; m-tolyl chloride
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (inhal.), Category 4 H332 Hazardous to the aquatic environment Chronic Hazard, Category 2 H411 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Xn; R20 N; R51/53 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS07 GHS09
Signal word (CLP) :	Warning
Hazard statements (CLP) :	H332 - Harmful if inhaled. H411 - Toxic to aquatic life with long lasting effects.
Precautionary statements (CLP) :	P273 - Avoid release to the environment.
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		3-CHLOROTOLUENE FOR SYNTHESIS
CAS No. :		108-41-8
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Assure fresh air breathing. Allow the victim to rest.
First-aid measures after skin contact :	Wash with plenty of water/…. Get immediate medical advice/attention.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth. Do not induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects after inhalation : Harmful if inhaled.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	Flammable liquid and vapour.
Explosion hazard :	May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting :	Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. No open flames. No smoking. Use special care to avoid static electric charges.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Avoid contact with skin and eyes. Do not breathe vapours. Provide good ventilation in process area to prevent formation of vapour.
Hygiene measures :	Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed. Use explosion-proof electrical/ventilating/lighting equipment.
Storage conditions :	Keep container tightly closed. Keep in fireproof place.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	[In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid
Molecular mass :	126.6 g/mol
Colour :	Light yellow.
Odour :	No data available
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	-48 °C
Freezing point :	No data available
Boiling point :	160 - 162 °C
Flash point :	52 °C
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	Flammable
Vapour pressure :	3.6 mbar at 20°C
Relative vapour density at 20°C :	No data available
Density :	1.072 g/cm3
Solubility :	Water: Slightly soluble in water
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Heat. Sparks.
10.5 Incompatible materials
Oxidizing agent.
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Inhalation: Harmful if inhaled.
Skin corrosion/irritation :	Not classified
Serious eye damage/irritation :	Not classified
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	Not classified
STOT-repeated exposure :	Not classified

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Toxic to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability :	3-CHLOROTOLUENE FOR SYNTHESIS (108-41-8) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	2238
UN-No. (IMDG) :	2238
UN-No. (IATA) :	2238
UN-No. (ADN) :	2238
UN-No. (RID) :	2238
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	CHLOROTOLUENES
Proper Shipping Name (IMDG) :	CHLOROTOLUENES
Proper Shipping Name (IATA) :	CHLOROTOLUENES
Proper Shipping Name (ADN) :	CHLOROTOLUENES
Proper Shipping Name (RID) :	CHLOROTOLUENES
Transport document description (ADR) :	UN 2238, CHLOROTOLUENES, 3, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 2238, CHLOROTOLUENES, 3, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 2238, CHLOROTOLUENES, 3, III ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 2238, CHLOROTOLUENES, 3, III ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 2238, CHLOROTOLUENES, 3, III ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	3
Danger labels :	3
IMDG
Transport hazard class(es) :	3
Danger labels :	3
IATA
Transport hazard class(es) :	3
Danger labels :	3
ADN
Transport hazard class(es) :	3
Danger labels :	3
RID
Transport hazard class(es) :	3
Danger labels :	3
14.4. Packing group
Packing group (ADR) :	III
Packing group (IMDG) :	III
Packing group (IATA) :	III
Packing group (ADN) :	III
Packing group (RID) :	III
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : F1 Limited quantities (ADR) : 5l Excepted quantities (ADR) : E1 Packing instructions (ADR) : P001, IBC03, LP01, R001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T2 Portable tank and bulk container special provisions (ADR) : TP1 Tank code (ADR) : LGBF Vehicle for tank carriage : FL Transport category (ADR) : 3 Special provisions for carriage - Packages (ADR) : V12 Special provisions for carriage - Operation (ADR) : S2 Hazard identification number (Kemler No.) : 30 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : 3Y
- Transport by sea
Packing instructions (IMDG) : P001, LP01 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T2 Tank special provisions (IMDG) : TP1 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-D Stowage category (IMDG) : A Flash point (IMDG) : 43°C to 47°C c.c. Properties and observations (IMDG) : Colourless to brown liquids. Flashpoint: 43°C to 47°C c.c. Immiscible with water. When involved in a fire, evolve toxic gases. Harmful by skin contact or by inhalation. Irritating to eyes and mucous membranes. MFAG-No : 129
- Air transport
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y344 PCA limited quantity max net quantity (IATA) : 10L PCA packing instructions (IATA) : 355 PCA max net quantity (IATA) : 60L CAO packing instructions (IATA) : 366 CAO max net quantity (IATA) : 220L ERG code (IATA) : 3L
- Inland waterway transport
Classification code (ADN) : F1 Limited quantities (ADN) : 5 L Excepted quantities (ADN) : E1 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EX, A Ventilation (ADN) : VE01 Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : F1 Excepted quantities (RID) : E1 Packing instructions (RID) : P001, IBC03, LP01, R001 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T2 Portable tank and bulk container special provisions (RID) : TP1 Tank codes for RID tanks (RID) : LGBF Transport category (RID) : 3 Special provisions for carriage – Packages (RID) : W12 Colis express (express parcels) (RID) : CE4 Hazard identification number (RID) : 30
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions 3-CHLOROTOLUENE FOR SYNTHESIS is not on the REACH Candidate List 3-CHLOROTOLUENE FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed
Denmark
Class for fire hazard : Class II-1 Store unit : 5 liter Classification remarks : R10 ; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Aquatic Chronic 2 Hazardous to the aquatic environment — Chronic Hazard, Category 2 H332 Harmful if inhaled. H411 Toxic to aquatic life with long lasting effects. R20 Harmful by inhalation R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment N Dangerous for the environment Xn Harmful