EHRLICH'S A REAGENT For Diazo Reaction

EHRLICH'S A REAGENT For Diazo Reaction

Synonyms :

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : EHRLICH’S A REAGENT
Catalogue No. : AL1987 Product form : Mixture
CAS Number : EC Number :
Grade : EC Index Number :
Chemical Formula : HSN Code : 38220090
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial For professional use only
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS07GHS07
Signal word (CLP) : Warning
Hazard statements (CLP) : H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H335 - May cause respiratory irritation.
Precautionary statements (CLP) : P261 - Avoid breathing vapours, spray, dust, fume, gas.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Not applicable
3.2. Mixture
Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP]
Water (CAS-No.) 7732-18-5 (EC-No.) 231-791-2 75 - 99 Not classified
Hydrochloric acid (CAS-No.) 7647-01-0 (EC-No.) 231-595-7 (EC Index-No.) 017-002-01-X 15 - 25 Skin Corr. 1B, H314 STOT SE 3, H335
Sulfamic acid (CAS-No.) 5329-14-6 (EC-No.) 226-218-8 (EC Index-No.) 016-026-00-0 1 - 5 Eye Irrit. 2, H319 Skin Irrit. 2, H315 Aquatic Chronic 3, H412
Full text of H-statements: see section 16

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Immediately call a
POISON CENTER/doctor. Call a POISON CENTER/doctor if you feel unwell.
First-aid measures after skin contact : Take off immediately all contaminated clothing. Rinse skin with water/shower.
Immediately call a POISON CENTER/doctor.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/effects after inhalation : May cause respiratory irritation.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3 Indication of any immediate medical attention and special treatment needed
General information : No additional information available

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Do not breathe vapours. Avoid contact with skin and eyes. Use only outdoors or in a well-ventilated area. Provide good ventilation in process area to prevent formation of vapour.
Hygiene measures : Wash contaminated clothing before reuse. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures : Comply with applicable regulations.
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or face shield
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid Colour
Colour : Clear Colorless.
Odour : No data available
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : 176 °C
Flash point : 164 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20°C : No data available
Solubility : Water: Miscible in water
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Air contact. Direct sunlight.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Not classified
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
STOT-single exposure : May cause respiratory irritation.
STOT-repeated exposure : Not classified

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1789
UN-No. (IMDG) : 1789
UN-No. (IATA) : 1789
UN-No. (ADN) : 1789
UN-No. (RID) : 1789
14.2. UN proper shipping name
Proper Shipping Name (ADR) : HYDROCHLORIC ACID
Proper Shipping Name (IMDG) : HYDROCHLORIC ACID
Proper Shipping Name (IATA) : HYDROCHLORIC ACID
Proper Shipping Name (ADN) : HYDROCHLORIC ACID
Proper Shipping Name (RID) : HYDROCHLORIC ACID
Transport document description (ADR) : UN 1789, HYDROCHLORIC ACID, 8, II
Transport document description (IMDG) : UN 1789, HYDROCHLORIC ACID, 8, II
Transport document description (IATA) : UN 1789, HYDROCHLORIC ACID, 8, II
Transport document description (ADN) : UN 1789, HYDROCHLORIC ACID, 8, II
Transport document description (RID) : UN 1789, HYDROCHLORIC ACID, 8, II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 8
Danger labels : 8
IMDG
Transport hazard class(es) : 8
Danger labels : 8
IATA
Transport hazard class(es) : 8
Danger labels : 8
ADN
Transport hazard class(es) : 8
Danger labels : 8
RID
Transport hazard class(es) : 8
Danger labels : 8
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : C1
Special provisions (ADR) : 520
Limited quantities (ADR) : 1l
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P001, IBC02
Mixed packing provisions (ADR) : MP15
Portable tank and bulk container
instructions (ADR)
: T8
Portable tank and bulk container special
provisions (ADR)
: TP2
Tank code (ADR) : L4BN
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Hazard identification number (Kemler No.) : 80
Orange plates :
Tunnel restriction code (ADR) : E
EAC code : 2R
- Transport by sea
Packing instructions (IMDG) : P001
IBC packing instructions (IMDG) : IBC02
IBC special provisions (IMDG) : B20
Tank instructions (IMDG) : T8
Tank special provisions (IMDG) : TP2
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-B
Stowage category (IMDG) : C
Properties and observations (IMDG) : Colourless liquid.An aqueous solution of the gas hydrogen chloride. Highly corrosive
to most metals. Causes burns to skin, eyes and mucous membranes.
MFAG-No : 157
- Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y840
PCA limited quantity max net quantity
(IATA)
: 0.5L
PCA packing instructions (IATA) : 851
PCA max net quantity (IATA) : 1L
CAO packing instructions (IATA) : 855
CAO max net quantity (IATA) : 30L
Special provisions (IATA) : A3
ERG code (IATA) : 8L
- Inland waterway transport
Classification code (ADN) : C1
Special provisions (ADN) : 520
Limited quantities (ADN) : 1 L
Excepted quantities (ADN) : E2
Carriage permitted (ADN) : T
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : C1
Special provisions (RID) : 520
Limited quantities (RID) : 1L
Excepted quantities (RID) : E2
Packing instructions (RID) : P001, IBC02
Mixed packing provisions (RID) : MP15
Portable tank and bulk container
instructions (RID)
: T8
Portable tank and bulk container special
provisions (RID)
: TP2
Tank codes for RID tanks (RID) : L4BN
Transport category (RID) : 2
Colis express (express parcels) (RID) : CE6
Hazard identification number (RID) : 80
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
Contains no REACH substances with Annex XVII restrictions
Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 3, severe hazard to water (Classification according to
AwSV, Annex 1)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : None of the components are listed
SZW-lijst van mutagene stoffen : None of the components are listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Borstvoeding
: None of the components are listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen-
Vruchtbaarheid
: None of the components are listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Ontwikkeling
: None of the components are listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of H- and EUH-statements:
Aquatic Chronic 3 Hazardous to the aquatic environment — Chronic Hazard, Category 3
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
Skin Corr. 1B Skin corrosion/irritation, Category 1B
Skin Irrit. 2 Skin corrosion/irritation, Category 2
STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H412 Harmful to aquatic life with long lasting effects.