SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	DICHLORO METHANE AR (methylene chloride)
Catalogue No. :	AL1714	Product form :	Substance
CAS Number :	75-09-2	EC Number :	200-838-9
Grade :		EC Index Number :	602-004-00-3
Chemical Formula :	CH2Cl2	HSN Code :	29031200
Synonyms :	Methylene chloride / DCM
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Laboratory chemicals, Manufacture of substances
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Carcinogenicity, Category 2 H351 Specific target organ toxicity Single exposure, Category 3, Narcosis H336 Specific target organ H335 toxicity Single exposure, Category 3, Respiratory tract irritation Specific target organ toxicity Repeated exposure, Category 2 H373 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.3; R40 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS07 GHS08
Signal word (CLP) :	Warning
Hazard statements (CLP) :	H315 - Causes skin irritation. H319 - Causes serious eye irritation. H335 - May cause respiratory irritation. H336 - May cause drowsiness or dizziness. H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure.
Precautionary statements (CLP) :	P261 - Avoid breathing vapours, dust, fume, gas. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		DICHLOROMETHANE AR/ACS
CAS No. :		75-09-2
EC Index No. :		602-004-00-3
EC No. :		200-838-9
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Assure fresh air breathing. If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
First-aid measures after skin contact :	Wash with plenty of water/…. Get immediate medical advice/attention.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth. Do not induce vomiting. Get medical advice/attention.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects : May cause damage to organs through prolonged or repeated exposure. Symptoms/effects after inhalation : May cause respiratory irritation. May cause drowsiness or dizziness. Symptoms/effects after skin contact : Causes skin irritation. Symptoms/effects after eye contact : Causes serious eye irritation. Symptoms/effects after ingestion : Harmful if swallowed. Chronic symptoms : Suspected carcinogen.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media :	Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	On land, sweep or shovel into suitable containers. Collect spillage.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Obtain special instructions before use. Avoid contact with skin and eyes. Do not breathe vapours. Take precautionary measures against static discharge.
Hygiene measures :	Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	[In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid Colour
Colour :	Clear Colorless.
Odour :	chloroform-like odor.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	0.71
Melting point :	-97 °C
Freezing point :	No data available
Boiling point :	39.8 - 40 °C
Flash point :	No data available
Auto-ignition temperature :	556 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	470.8 hPa at 20°C
Relative vapour density at 20°C :	No data available
Density :	1.325 g/cm3
Solubility :	Water: Slightly soluble
Log Pow :	1.25
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Overheating.
10.5 Incompatible materials
Oxidizing agent.
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Not classified
Skin corrosion/irritation :	Causes skin irritation.
Serious eye damage/irritation :	Causes serious eye irritation.
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Suspected of causing cancer.
STOT-single exposure :	May cause drowsiness or dizziness. May cause respiratory irritation.
STOT-repeated exposure :	May cause damage to organs through prolonged or repeated exposure.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	DICHLOROMETHANE AR/ACS (75-09-2) Log Pow 1.25
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1593
UN-No. (IMDG) :	1593
UN-No. (IATA) :	1593
UN-No. (ADN) :	1593
UN-No. (RID) :	1593
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	DICHLOROMETHANE
Proper Shipping Name (IMDG) :	DICHLOROMETHANE
Proper Shipping Name (IATA) :	DICHLOROMETHANE
Proper Shipping Name (ADN) :	DICHLOROMETHANE
Proper Shipping Name (RID) :	DICHLOROMETHANE
Transport document description (ADR) :	UN 1593, DICHLOROMETHANE, 6.1, III
Transport document description (IMDG) :	UN 1593, DICHLOROMETHANE, 6.1, III
Transport document description (IATA) :	UN 1593, DICHLOROMETHANE, 6.1, III
Transport document description (ADN) :	UN 1593, DICHLOROMETHANE, 6.1, III
Transport document description (RID) :	UN 1593, DICHLOROMETHANE, 6.1, III
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	6.1
Danger labels :	6.1
IMDG
Transport hazard class(es) :	6.1
Danger labels :	6.1
IATA
Transport hazard class(es) :	6.1
Danger labels :	6.1
ADN
Transport hazard class(es) :	6.1
Danger labels :	6.1
RID
Transport hazard class(es) :	6.1
Danger labels :	6.1
14.4. Packing group
Packing group (ADR) :	III
Packing group (IMDG) :	III
Packing group (IATA) :	III
Packing group (ADN) :	III
Packing group (RID) :	III
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : T1 Special provisions (ADR) : 516 Limited quantities (ADR) : 5l Excepted quantities (ADR) : E1 Packing instructions (ADR) : P001, IBC03, LP01, R001 Special packing provisions (ADR) : B8 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Packages (ADR) : V12 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S9 Hazard identification number (Kemler No.) : 60 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2Z
- Transport by sea
Packing instructions (IMDG) : P001, LP01 IBC packing instructions (IMDG) : IBC03 IBC special provisions (IMDG) : B8 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP2 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-A Stowage category (IMDG) : A Properties and observations (IMDG) : Colourless, volatile liquid with heavy vapours. Boiling point: 40°C. When involved in a fire, evolves extremely toxic fumes (phosgene). Toxic if swallowed, by skin contact or by inhalation. MFAG-No : 160
- Air transport
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y642 PCA limited quantity max net quantity (IATA) : 2L PCA packing instructions (IATA) : 655 PCA max net quantity (IATA) : 60L CAO packing instructions (IATA) : 663 CAO max net quantity (IATA) : 220L ERG code (IATA) : 6L
- Inland waterway transport
Classification code (ADN) : T1 Special provisions (ADN) : 516, 802 Limited quantities (ADN) : 5 L Excepted quantities (ADN) : E1 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP, TOX, A Ventilation (ADN) : VE02 Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : T1 Special provisions (RID) : 516 Excepted quantities (RID) : E1 Packing instructions (RID) : P001, IBC03, LP01, R001 Special packing provisions (RID) : B8 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage – Packages (RID) : W12 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE8 Hazard identification number (RID) : 60
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions DICHLOROMETHANE AR/ACS is not on the REACH Candidate List DICHLOROMETHANE AR/ACS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 2, significant hazard to water (Classification according to AwSV; ID No. 149) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Carc. 2 Carcinogenicity, Category 2 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Narcosis STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. R40 Limited evidence of a carcinogenic effect