SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	ETHYL CHLORO ACETATE (mono)
Catalogue No. :	AL2064	Product form :	Substance
CAS Number :	105-39-5	EC Number :	203-294-0
Grade :		EC Index Number :	607-070-00-7
Chemical Formula :	C4H7ClO2	HSN Code :	29153990
Synonyms :	Chloroacetic Acid ethyl ester; Ethylalpha-chloroacetate; Ethyl chloroethanoate; Ethylmonochloracetate; Ethyl monochloroacetate
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial. For professional use only.
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, Category 3 H226 Acute toxicity (oral), Category 3 H301 Acute toxicity (dermal), Category 3 H311 Acute toxicity (inhal.), Category 3 H331 Serious eye damage/eye irritation, Category 1 H318 Hazardous to the aquatic environment Acute Hazard, Category 1 H400 Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
T; R23/24/25 N; R50 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS02 GHS05 GHS06 GHS09
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H226 - Flammable liquid and vapour H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H318 - Causes serious eye damage H400 - Very toxic to aquatic life
Precautionary statements (CLP) :	P261 - Avoid breathing dust, fume, gas, spray, vapours P273 - Avoid release to the environment P280 - Wear protective gloves, protective clothing, eye protection, face protection P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or doctor/physician P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P311 - Call a doctor
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		ETHYL CHLOROACETATE FOR SYNTHESIS
CAS No. :		105-39-5
EC Index No. :		607-070-00-7
EC No. :		203-294-0
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove victim to fresh air and keep at rest in a position comfortable for breathing. Allow the victim to rest. Get medical advice/attention if you feel unwell.
First-aid measures after skin contact :	Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Wash contaminated clothing before reuse. Get medical advice/attention.
First-aid measures after eye contact :	Rinse eyes with water as a precaution. Rinse cautiously with water for several minutes. Get immediate medical advice/attention.
First-aid measures after ingestion :	Rinse mouth. Obtain emergency medical attention. Immediately call a POISON CENTER or doctor/physician.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries after skin contact : Repeated exposure to this material can result in absorption through skin causing significant health hazard. Toxic in contact with skin. Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms/injuries after ingestion : Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	No additional information available

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Water spray. Dry powder. Carbon dioxide. Foam.
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	Flammable liquid and vapour.
Explosion hazard :	May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting :	No additional information available

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. No naked lights. No smoking. Use special care to avoid static electric charges.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Avoid contact with skin and eyes. Do not breathe vapours. Keep away from sources of ignition - No smoking. Use only non-sparking tools. Provide good ventilation in process area to prevent formation of vapour.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed. Use explosion-proof electrical/ventilating/lighting/… equipment.
Storage conditions :	Keep in fireproof place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid Colour
Colour :	Clear Colorless.
Odour :	fruity,pungent.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	-26 °C
Freezing point :	No data available
Boiling point :	143 °C
Flash point :	54 °C Critical temperature : 344.85 °C
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	4.4 hPa at 20 °C
Relative vapour density at 20°C :	4.23
Density :	1.1498 g/cm3
Solubility :	Water: Insoluble
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Heat.
10.5 Incompatible materials
Strong acids. Strong bases.
10.6 Hazardous decomposition products
Carbon dioxide. Carbon monoxide. fume.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Toxic if swallowed. Dermal: Toxic in contact with skin. Inhalation: Toxic if inhaled.
Skin corrosion/irritation :	Not classified
Serious eye damage/irritation :	Causes serious eye damage.
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
Reproductive toxicity :	Not classified
Specific target organ toxicity (single exposure) :	Not classified
Specific target organ toxicity (repeated exposure) :	Not classified
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Toxic if swallowed. Toxic in contact with skin.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Very toxic to aquatic life.
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...
Ecology - waste materials :	Hazardous waste due to toxicity.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1181
UN-No. (IMDG) :	1181
UN-No. (IATA) :	1181
UN-No. (ADN) :	1181
UN-No. (RID) :	1181
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	ETHYL CHLOROACETATE
Proper Shipping Name (IMDG) :	ETHYL CHLOROACETATE
Proper Shipping Name (IATA) :	ETHYL CHLOROACETATE
Proper Shipping Name (ADN) :	ETHYL CHLOROACETATE
Proper Shipping Name (RID) :	ETHYL CHLOROACETATE
Transport document description (ADR) :	UN 1181, ETHYL CHLOROACETATE, 6.1 (3), II ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 1181, ETHYL CHLOROACETATE, 6.1 (3), II ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 1181, ETHYL CHLOROACETATE, 6.1 (3), II ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 1181, ETHYL CHLOROACETATE, 6.1 (3), II ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 1181, ETHYL CHLOROACETATE, 6.1 (3), II ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	6.1 (3)
Danger labels :	6.1, 3
IMDG
Transport hazard class(es) :	6.1 (3)
Danger labels :	6.1, 3
IATA
Transport hazard class(es) :	6.1 (3)
Danger labels :	6.1, 3
ADN
Transport hazard class(es) :	6.1 (3)
Danger labels :	6.1, 3
RID
Transport hazard class(es) :	6.1 (3)
Danger labels :	6.1, 3
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : TF1 Limited quantities (ADR) : 100ml Excepted quantities (ADR) : E4 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : FL Transport category (ADR) : 2 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S2, S9, S19 Hazard identification number (Kemler No.) : 63 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : 2W APP code : A(fl)
- Transport by sea
Limited quantities (IMDG) : 100 ml Excepted quantities (IMDG) : E4 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP2 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-D Stowage category (IMDG) : A Flash point (IMDG) : 54°C c.c. MFAG-No : 155
- Air transport
PCA Excepted quantities (IATA) : E4 PCA Limited quantities (IATA) : Y641 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 654 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 662 CAO max net quantity (IATA) : 60L ERG code (IATA) : 6F
- Inland waterway transport
Not regulated
- Rail transport
Not regulated
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions ETHYL CHLOROACETATE FOR SYNTHESIS is not on the REACH Candidate List ETHYL CHLOROACETATE FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (KBwS-Beschluss; WGK No 1129) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Class for fire hazard : Class II-1 Store unit : 5 liter Classification remarks : R10 ; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases: Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3 Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3 Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3 Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Flam. Liq. 3 Flammable liquids, Category 3 H226 Flammable liquid and vapour H301 Toxic if swallowed H311 Toxic in contact with skin H318 Causes serious eye damage H331 Toxic if inhaled H400 Very toxic to aquatic life R23/24/25 Toxic by inhalation, in contact with skin and if swallowed R50 Very toxic to aquatic organisms N Dangerous for the environment T Toxic