SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	ETHYL BROMOACETATE (for synthesis)
Catalogue No. :	AL2058	Product form :	Substance
CAS Number :	105-36-2	EC Number :
Grade :		EC Index Number :
Chemical Formula :	C4H7BrO2	HSN Code :	29153990
Synonyms :	Bromoacetic acid ethyl ester
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (dermal), Category 1 H310 Acute toxicity (inhal.), Category 2 H330 Acute toxicity (oral), Category 1 H300 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
T+; R26/27/28 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS06
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H300+H310+H330 - Fatal if swallowed, in contact with skin or if inhaled
Precautionary statements (CLP) :	P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P264 - Wash hands, forearms and face thoroughly after handling. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P284 - Wear respiratory protection. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER/doctor P302+P350 - IF ON SKIN: Gently wash with plenty of soap and water.
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		ETHYL BROMOACETATE FOR SYNTHESIS
CAS No. :		105-36-2
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Allow the victim to rest.
First-aid measures after skin contact :	Gently wash with plenty of soap and water. Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Get medical advice/attention.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention.
First-aid measures after ingestion :	Rinse mouth. Get immediate medical advice/attention. Do not induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects after inhalation : Fatal if inhaled. Symptoms/effects after skin contact : Fatal in contact with skin. Symptoms/effects after ingestion : Fatal if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Water spray. Dry powder. Carbon dioxide. Foam.
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard :
Explosion hazard :
5.3 Advice for firefighters
Protection during firefighting :	Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Avoid contact with skin and eyes. Do not breathe vapours. Provide good ventilation in process area to prevent formation of vapour.
Hygiene measures :	Do not eat, drink or smoke when using this product.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Keep container tightly closed. Keep container closed when not in use. Incompatible products : Strong acids. Strong bases.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	[In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid
Molecular mass :	167.01 g/mol
Colour :	Colorless to pale yellow.
Odour :	pungent odour.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	No data available
Freezing point :	No data available
Boiling point :	159 °C
Flash point :	47 °C
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	2.6 mm Hg at 250C
Relative vapour density at 20°C :	5.8
Density :	1.506 g/cm3
Solubility :	Water: Insoluble
Log Pow :	1.12
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5 Incompatible materials
Strong acids. Strong bases.
10.6 Hazardous decomposition products
Carbon dioxide. Carbon monoxide. fume.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Dermal: Fatal in contact with skin. Inhalation: Fatal if inhaled. Oral: Fatal if swallowed.
Skin corrosion/irritation :	Not classified
Serious eye damage/irritation :	Not classified
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	Not classified
STOT-repeated exposure :	Not classified
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Fatal if swallowed. Fatal in contact with skin.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	ETHYL BROMOACETATE FOR SYNTHESIS (105-36-2) Log Pow 1.12
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Ecology - waste materials :	Hazardous waste due to toxicity.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1603
UN-No. (IMDG) :	1603
UN-No. (IATA) :	1603
UN-No. (ADN) :	1603
UN-No. (RID) :	1603
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	ETHYL BROMOACETATE
Proper Shipping Name (IMDG) :	ETHYL BROMOACETATE
Proper Shipping Name (IATA) :	ETHYL BROMOACETATE
Proper Shipping Name (ADN) :	ETHYL BROMOACETATE
Proper Shipping Name (RID) :	ETHYL BROMOACETATE
Transport document description (ADR) :	UN 1603, ETHYL BROMOACETATE, 6.1 (3), II
Transport document description (IMDG) :	UN 1603, ETHYL BROMOACETATE, 6.1 (3), II
Transport document description (IATA) :	UN 1603, ETHYL BROMOACETATE, 6.1 (3), II
Transport document description (ADN) :	UN 1603, ETHYL BROMOACETATE, 6.1 (3), II
Transport document description (RID) :	UN 1603, ETHYL BROMOACETATE, 6.1 (3), II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	6.1 (3)
Danger labels :	6.1, 3
IMDG
Transport hazard class(es) :	6.1 (3)
Danger labels :	6.1, 3
IATA
Transport hazard class(es) :	6.1 (3)
Danger labels :	6.1, 3
ADN
Transport hazard class(es) :	6.1 (3)
Danger labels :	6.1, 3
RID
Transport hazard class(es) :	6.1 (3)
Danger labels :	6.1, 3
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : TF1 Limited quantities (ADR) : 100ml Excepted quantities (ADR) : E0 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : FL Transport category (ADR) : 2 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S2, S9, S19 Hazard identification number (Kemler No.) : 63 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : 2W APP code : A(fl)
- Transport by sea
Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP2 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-D Stowage category (IMDG) : D Stowage and handling (IMDG) : SW2 Flash point (IMDG) : 58°C c.c. Properties and observations (IMDG) : Colourless, flammable liquid evolving irritating vapour ("Tear Gas"). Flashpoint: 58°C c.c. Toxic if swallowed, by skin contact or by inhalation. MFAG-No : 155
- Air transport
PCA Limited quantities (IATA) : Forbidden PCA limited quantity max net quantity (IATA) : Forbidden PCA packing instructions (IATA) : Forbidden PCA max net quantity (IATA) : Forbidden CAO packing instructions (IATA) : Forbidden CAO max net quantity (IATA) : Forbidden Special provisions (IATA) : A2 ERG code (IATA) : 6F
- Inland waterway transport
Classification code (ADN) : TF1 Special provisions (ADN) : 802 Limited quantities (ADN) : 100 ml Excepted quantities (ADN) : E0 Equipment required (ADN) : PP, EP, EX, TOX, A Ventilation (ADN) : VE01, VE02 Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : TF1 Excepted quantities (RID) : E0 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE5 Hazard identification number (RID) : 63
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions ETHYL BROMOACETATE FOR SYNTHESIS is not on the REACH Candidate List ETHYL BROMOACETATE FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed
Denmark
Class for fire hazard : Class II-1 Store unit : 5 liter Classification remarks : R10 ; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information
Full text of R-, H- and EUH-statements: Acute Tox. 1 (Dermal) Acute toxicity (dermal), Category 1 Acute Tox. 1 (Oral) Acute toxicity (oral), Category 1 Acute Tox. 2 (Inhalation) Acute toxicity (inhal.), Category 2 H300 Fatal if swallowed. H310 Fatal in contact with skin. H330 Fatal if inhaled. R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed T+ Very toxic