HYDROGEN PEROXIDE SOLUTION

HYDROGEN PEROXIDE SOLUTION

Synonyms : Dihydrogen dioxide; Hydrogen dioxide; Hydroperoxide

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : HYDROGEN PEROXIDE (100 Vol.) solution (30% w/v H2O2)
Catalogue No. : AL2469 Product form : Mixture
CAS Number : 7722-84-1 EC Number :
Grade : EC Index Number :
Chemical Formula : HSN Code : 28470000
Synonyms : Dihydrogen dioxide
Chemical Structure :
Industrial;For professional use only :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial For professional use only
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Mixture/Substance: SDS EU 2015: According to Annex II
of Regulation (EC) No. 453/2010 (REACH Annex II)
Serious eye damage/eye
irritation, Category 1
H318
Acute toxicity (oral),
Category 4
H302
Full text of classification categories and H statements : see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS05GHS05 GHS07GHS07
Signal word (CLP) : Danger
Hazard statements (CLP) : H302 - Harmful if swallowed
H318 - Causes serious eye damage
Precautionary statements (CLP) : P280 - Wear eye protection, face protection, protective clothing, protective gloves
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Not applicable
CAS No. : 7722-84-1
3.2. Mixture
Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP]
Water (CAS No) 7732-18-5 (EC no) 231-791-2 50 - 75 Not classified
Hydrogen peroxide (CAS No) 7722-84-1 (EC no) 231-765-0 (EC index no) 008-003-00-9 25 - 50 Eye Dam. 1, H318 Acute Tox. 4 (Oral), H302
Acetanilide (CAS No) 103-84-4 (EC no) 203-150-7 0.01 - 1 Acute Tox. 4 (Oral), H302
Full text of H-phrases: see section 16

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. If you feel unwell,
seek medical advice.
First-aid measures after skin contact : Take off contaminated clothing. Gently wash with plenty of soap and water. If skin
irritation occurs: Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON CENTER or
doctor/physician.
First-aid measures after ingestion : Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/injuries after eye contact : Causes serious eye damage.
Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Dry chemical, CO2, or water spray or regular foam.
Unsuitable extinguishing media : Carbon dioxide (CO2).
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills
with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid Colour
Colour : Clear Colorless.
Odour : slight acrid odor.
Odour threshold : No data available
pH value : 6 - 8 at 25 °C
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : 25 mm Hg at 300C
Relative vapour density at 20°C : 1.17
Density : 1.11 g/cm3
Solubility : Water: Infinitely soluble
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Oral: Harmful if swallowed.
ATE CLP (oral) 500 mg/kg bodyweight
Skin corrosion/irritation : Not classified
pH: 6 - 8 at 25 °C
Serious eye damage/irritation : Causes serious eye damage.
pH: 6 - 8 at 25 °C
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful if swallowed.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2014
UN-No. (IMDG) : 2014
UN-No. (IATA) : 2014
UN-No. (ADN) : 2014
UN-No. (RID) : 2014
14.2. UN proper shipping name
Proper Shipping Name (ADR) : HYDROGEN PEROXIDE, AQUEOUS SOLUTION
Proper Shipping Name (IMDG) : HYDROGEN PEROXIDE, AQUEOUS SOLUTION
Proper Shipping Name (IATA) : HYDROGEN PEROXIDE, AQUEOUS SOLUTION
Proper Shipping Name (ADN) : HYDROGEN PEROXIDE, AQUEOUS SOLUTION
Proper Shipping Name (RID) : HYDROGEN PEROXIDE, AQUEOUS SOLUTION
Transport document description (ADR) : UN 2014, HYDROGEN PEROXIDE, AQUEOUS SOLUTION, 5.1 (8), II
Transport document description (IMDG) : UN 2014, HYDROGEN PEROXIDE, AQUEOUS SOLUTION, 5.1 (8), II
Transport document description (IATA) : UN 2014, HYDROGEN PEROXIDE, AQUEOUS SOLUTION, 5.1 (8), II
Transport document description (ADN) : UN 2014, HYDROGEN PEROXIDE, AQUEOUS SOLUTION, 5.1 (8), II
Transport document description (RID) : UN 2014, HYDROGEN PEROXIDE, AQUEOUS SOLUTION, 5.1 (8), II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 5.1 (8)
Danger labels : 5.1, 8
IMDG
Transport hazard class(es) : 5.1 (8)
Danger labels : 5.1, 8
IATA
Transport hazard class(es) : 5.1 (8)
Danger labels : 5.1, 8
ADN
Transport hazard class(es) : 5.1 (8)
Danger labels : 5.1, 8
RID
Transport hazard class(es) : 5.1 (8)
Danger labels : 5.1, 8
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : OC1
Limited quantities (ADR) : 1L
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P504, IBC02
Special packing provisions (ADR) : PP10, B5
Mixed packing provisions (ADR) : MP15
Portable tank and bulk container
instructions (ADR)
: T7
Portable tank and bulk container special
provisions (ADR)
: TP2, TP6, TP24
Tank code (ADR) : L4BV(+)
Tank special provisions (ADR) : TU3, TC2, TE8, TE11, TT1
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV24
Hazard identification number (Kemler No.) : 58
Orange plates :
Tunnel restriction code (ADR) : E
EAC code : 2P
- Transport by sea
Limited quantities (IMDG) : 1 L
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P504
Packing provisions (IMDG) : PP10
IBC packing instructions (IMDG) : IBC02
IBC special provisions (IMDG) : B5
Tank instructions (IMDG) : T7
Tank special provisions (IMDG) : TP2, TP6, TP24
EmS-No. (Fire) : F-H
EmS-No. (Spillage) : S-Q
Stowage category (IMDG) : D
Stowage and handling (IMDG) : SW1
Segregation (IMDG) : SG16, SG59, SG72
MFAG-No : 140
- Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y540
PCA limited quantity max net quantity
(IATA)
: 0.5L
PCA packing instructions (IATA) : 550
PCA max net quantity (IATA) : 1L
CAO packing instructions (IATA) : 554
CAO max net quantity (IATA) : 5L
ERG code (IATA) : 5C
- Inland waterway transport
Not regulated
- Rail transport
Not regulated
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
Contains no substances with Annex XVII restrictions
Contains no REACH candidate substance
Contains no REACH Annex XIV substances.
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 1, slightly hazardous to water (Classification according to
AwSV, Annex 1)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of H- and EUH-phrases:
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Eye Dam. 1 Serious eye damage/eye irritation, Category 1
H302 Harmful if swallowed
H318 Causes serious eye damage